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2., Ammonia, C,H,OH, R-X+ NH3, →R-NH, + HX, 1° Amine, If alkyl halide is in excess, then 2° and 3° amines, Not.., and even quaternary salts are also formed., NH,, RX-, alcohol, RX, RNH,, R,NH, 1°Amine, 2°Amine, RX, RX, R,N, (Quaternary salt), 3°Amine, This reaction is called Hofmann ammonolysis of alkyl halides.